The 54-year-old joins the panel alongside Will.i.am, Kaiser Chiefs front man Ricky Wilson, and singer Paloma Faith.
During a battle of who has worked with bigger names, the King Of Everything singer shocked the live studio audience when he revealed HE'S SLEPT WITH PRINCE.
Yeah, that Prince!
According to a source, here's how it went down:
Boy George boasted about working with some of the best in the business:
"I have duetted with some of the greatest soul singers in history including Luther Vandross and Smokey Robinson."
To which Paloma rebutted:
"Well OK, if we're throwing big soul names out there I've performed with Prince."
And… BG reportedly quipped: